we have prepared and identified as a single-phase the new high- t c type superconductor y 2 ba 1. The resistive superconducting onset occurs at 82 k and zero resistance at 78 k. Diamagnetism and meissner effect sets in at low fields and magnetic superconducting onset starts at 82 k.
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A new high-temperature and nontoxic superconductor family of cu 1- x ba 2 ca n-1 cu n o 2 n4- with critical temperature (t c)116 k was discovered. These materials were prepared by the high-pressure technique. A superconductor sample with the highest t c contains mainly a cu 1- x ba 2 ca 3 cu 4 o 12- phase. The t c value of the cu 1- x ba 2 ca 3 cu 4 o 12- phase is 116.
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